报告人简历

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报告人简历

 

 CURRICULUM VITA

 Name:

 Birthday: Nationality: Marital Status:

  1(A) Education:

 B.A., 1973 Chemistry

 Dr. of Science., 1978 Dept. of Chemistry

 Dr. of Pharmacy, 1986

 Dept of Pharmacy

 Thesis Title of Dr. Sci.:

 Nagao Kobayashi Jan. 21, 1950 Japan Married, two daughters (28 and 26)

  Shinshu University Nagano, Japan

  Tohoku University Sendai, Miyagi 980-8578 Tohoku University Sendai, Miyagi 980-8578

 Magnetic Circular Dichroism Study of Peroxidase and Catalase (Advisor: M. Hatano)

 Thesis Title of Dr. Pharm. Electrocatalytic Reduction of Molecular Oxygen Using Wataer-Soluble or Immobilized Iron and Cobalt Porphyrins and Phthalocyanines (Advisor: T. Osa)

 1(B) Work Experience:

 1.

 Teaching Assistant/Graduate Student, Pharmaceutical Inst. Tohoku University, 1978-1983. 2.

 Visiting

 Scientist (Ohio State Univ.- JSPS Fellowship), 1979. 3. Assistant professor, Chemical Research Inst., Tohoku University, 1984-1985. 4. Assistant professor, Pharmaceutical Institute, 1986-1995. 5. Visiting

 Professor, ESPCI, Paris, France, 1994.(this is a place where Curie discovered Radium) 6. Professor, Dept. of Chemistry, Tohoku University, 1995-2009.

 2. Research Areas a. Electroreduction of oxygen b. Design and synthesis of low-symmetry giant aromatic molecules c. Spectroscopic properties of chromophores (absorption, magnetic circular dichroism,

 circular dichroism, IR, fluorescence spectroscopy) d. Understanding of spectral properties by molecular orbital calculations e. Application of giant macrocyclic compounds for photodynamic therapy and deodrants

 3. Publications and presentation in international conference : Original Papers: About 350 in the field of porphyrins, phthalocyanines and cyclodextrins. Chapter and Review Articles: 55. Textbook: CD and MCD Spectroscopy for Organic Chemists

  (from Royal Society of Chemistry, England, 2012) Presentation in international conference: About 200 times, and mostly invited oral presentation.

 ● Publications during the last five years. (A) Original Papers 1) meso-Aryl-Subporphyrins N. Kobayashi, Yuichi Takeuchi, and Atsushi Matsuda Angew. Chem. Int. Ed. 46, 758-760 (2007). 2) Superstructure Formation and Rearrangement in the Adlayer of a Rare-Earth Metal Triple-Decker Sandwich Complex at the Electrochemical Interface.

 S. Yoshimoto, T. Sawaguchi, W. Su, J. Jiang, and N. Kobayashi Angew. Chem. Int. Ed. 46, 1071-1074 (2007). 3) The Q Absorption Band of the Excited Triplet Phthalocyanine Dimer. K. Ishii, M. Iwasaki, and N. Kobayashi

 W. S. Durfee Chem. Phys. Lett. 436, 94-98 (2007). 4) anti-[2,2](1,4)Phthalocyaninophane: Spectroscopic Evidence for Transannular Interaction in the Excited States Y. Asano, A. Muranaka, A. Fukasawa, T. Hatano, M. Uchiyama, and N. Kobayashi J. Am. Chem. Soc. 129, 4516-4517 (2007) 5)

  Tetraazachlorin-C60 Conjugates: On-Off Control of electronic Communication Enabled by Push-Pull

  Substituents T. Fukuda, S. Masuda, and N. Kobayashi J. Am. Chem. Soc. 129, 7402-7409 (2007). 6)

  Synthesis and Charactrization of meso-Triarylsubporphyrins Y. Takeuchi, A. Matsuda, and N. Kobayashi J. Am. Chem. Soc. 129, 8271-8281 (2007) 7) Quantum Chemical Studies on Giant Aromatic Molecules

 K. Nakai, H. Kono, Y. Fujimura and N. Kobayashi

 SENAC 40, 31-36 (2007). 8) Metal Phthalocyanine Showing Four-Peak Q-Band Similar to Metal-Free Phthalocyanines: Nickel 1,4-Di(Trifluorosufonyl)phthalocaynine

 K. Nakai, J. Usami, and N. Kobayashi

 J. Porphyrins Phthalocyanines, 11, 222-227 (2007). 9) Silica gel-Supported Photofunctional Silicon Phthalocyanine Complexes: Photodesorption of Molecular Oxygen by Singlet Oxygen Generation.

 K. Ishii, M. Shiine, Y. Kikukawa, N. Kobayashi, T. Shiragami, J. Matsumoto, M. Yasuda, H. Suzuki, and H. Yokoi

 Chem. Phys. Lett. 448, 264-267 (2007). 10) Electronic Structures and Molecular Orbital Calculations of Oppositely Dinaphthalo- and Dianthraco- Substituted D2h Type Metal-Free Phthalocyanine Congeners.

 O. Matsushita, A. Muranaka, Y. Kobayashi, and N. Kobayashi

 Heterocycles, 74, 321-329 (2007). 11) Synthesis and Electronic Structures of D2h-Symmetry Tetrabenzoporphyrins.

 A. Muranaka, O. Matsushita, M. Numao, and N. Kobayashi

 Tet. Lett. 49, 1856-1859 (2008). 12) Metal Effects on Electronic Structures of Directly Linked Tribenzoetraazachlorin-Fullerene Conjugates.

 T. Fukuda, S. Masuda, N. Hashimoto, and N. Kobayashi

 Inorg. Chem. 47, 2576-2580 (2008)

 13) Optically Active Mixed (Phthalocyaninato)(porphyrinato) Rare Earth Double-Decker Complexes. Synthesis, Spectroscopy, and Solvent Dependent Molecular Conformation.

 X. Zhang, A. Muranaka, W. Lv, Y. Zhang, Y. Bian, J. Jiang, and N. Kobayashi

 Chem. Eur. J. 14, 4667-4674 (2008). 14) Electronic Structures of Azulene-Fused Porphyrins as Seen by Magnetic Circular Dichroism and TD-DFT Calculations.

 K. Nakai, K. Kurotobi, A. Osuka, M. Uchiyama, and N. Kobayashi

 J. Inorg. Bio. Chem. 102, 466-471 (2008). 15) Magnetic Circular Dichroism Spectroscopy of Cobalt Tetraphenyltetraacenaphthoporphyrin.

 J. Mack, Y. Asano, N. Kobayashi, and M. J. Stillman

 J. Inorg. Bio. Chem. 102, 472-479 (2008). 16) Control of Photobleaching in Photodynamic Therapy Using Photodecarbonylation Reaction of Ruthenium Phthalocyanine Complexes via Stepwise Two-Photon Excitation K. Ishii, M. Shiine, Y. Shimizu. S. Hoshino. H. Abe, K. Sogawa, and N. Kobayashi

 J. Phys. Chem. B, 112, 3138-3143 (2008). 17) meso-Aryl Tribenzosubporphyrin- A Totally Substituted Subporphyrin Species.

 E. A. Makarova, S. Shimizu, A. Matsuda, E. A. Luk’yanets, and N. Kobayashi

 Chem. Commun. 2109-2111 (2008). 18) Application of MCD Spectroscopy and TD-DFT to Nonplanar Core-Modified Tetrabenzoporphyrins: Effect of Reduced Symmetry on Nonplanar Porphyrinoids.

 J. Mack, M. Bunya, Y. Shimizu, H. Uoyama, N. Komobuchi, T. Okujima, H. Uno, S. Ito, M. J. Stillman, N. Ono, and N. Kobayashi

 Chem. Eur. J. 14, 5001-5020 (2008).

 page 2

 W. S. Durfee 19) Detection of Unusual DHOMO<DLUMO Relationship in Tetraphyrrolic cis- and trans-Doubly N-Confused Porphyrins.

 A. Muranaka, S. Hommma, H. Furuta, and N. Kobayashi

 Chem. Phys. Lett. 460, 495-498 (2008). 20) Solid-phase synthesis of phthalocyanine and tetraazaporphyrin triangular prisms

 A. Muranaka, K. Yoshida, Y. Akagi, H. Naka, M. Uchiyama, Y. Kondo, and N. Kobayashi

 Tet. Lett. 49, 5084-5086 (2008). 21) A Discrete Supramolecular Assembly Composed of Two Saddle-Distorted Zinc(II)-Phthalocyanine Complexes and a Doubly Protonated Porphyrin with Saddle-Distortion Undergoing Efficient Photoinduced Electron Transfer

 T. Kojima, T. Honda, K. Ohkubo, M. Shiro, T. Kusukawa, T. Fukuda, N. Kobayashi, and S. Fukuzumi

 Angew. Chem. 47, 6712-6716 (2008).

 22) Synthesis of N,N-difluoroboryl Complexes of 3,3’Diarylazadiisoindolylmethenes.

 V. F. Donyagina, S. Shimizu, N. Kobayashi, and E. A. Luk’yanets

 Tet. Lett. 49, 6152-6154 (2008). 23) Synthesis and Photophysical Properties of Silica-Gel-Supported Photofunctional

  (Phthalocyaninato)silicon Complexes

 K. Ishii, Y. Kikukawa, M. Shiine, N. Kobayashi, T. Tsuru, Y. Sakai, and A. Sakoda

 Eur. J. Inog. Chem. 2975-2981 (2008). 24) Unambiguous Identification of Möbius Aromaticity for meso-Aryl Substituted

 [28]Hexaphyrins(1.1.1.1.1.1)

 J. Sankar, S. Mori, S. Saito, H. Rath, M. Suzuki, Y. Inokuma, H. Shinokubo, K. S. Kim, Z. S. Yoon, J. -Y. Shin, J. M. Lim, Y. Matsuzaki, O. Matsushita, A. Muranaka, N. Kobayashi, D. Kim, and A. Osuka

 J. Am. Chem. Soc. 130, 13568-13579 (2008). 25) Absolute Configuration and Origin of Chiroptical Properties of Three-Layered [3,3]Paracyclophane: Synthesis, Optical Resolution, and Density Functional Theory Calculations.

 A. Muranaka, M. Shibahara, M. Watanabe, T. Matsumoto, T. Shinmyouzu, and N. Kobayashi

 J. Org. Chem. 73, 9125-9128 (2008). 26) A Facile One Pot Synthesis of meso-Aryl-Substituted [14]Triphyrin(2.1.1) Z. L. Xue, Z. Shen, J. Mack, D. Kuzuhara, H. Yamada, T. Okujima, N. Ono, X. Z. You, and N. Kobayashi

 J. Am. Chem. Soc. 130, 16478-16479 (2008). 27) Sandwich-Type Heteroleptic opposite-(Diazaporphyrinato)cerium Complexes: Synthesis, Spectroscopy,

  Structure, and Electrochemistry

 N. Pan, Y. Bian, M. Yokoyama, R. Li, T. Fukuda, S. Neya, J. Jiang, and N. Kobayashi

 Eur. J. Inorg. Chem. 2008, 5519-5523 . 28) The MCD Spectroscopy of Corrolazines and Triazatetrabenzocorroles.

 J. Mack, M. Bunya, D. Lansky, D. P. Goldberg, and N. Kobayashi

 Heterocycles 76, 1369-1380 (2008). 29) Effect of Periodic Replacement of the Heteroatom on ther Structure and Spectroscopic Properties of Indole and Benzofuran Derivatives. A. Muranaka, S. Yasuike, C. –Y. Liu, J. Kurita, N. Kakusawa, T. Tsuchiya, M. Okuda, N. Kobayashi, Y. Matsumoto, K. Yoshida, D. Hashizume, and M. Uchiyama J. Phys. Chem. A, 113, 464-473 (2009). 30) Intramolecular Axial Ligation of Zinc Porphyrin Cores with Triazole Links within Dendrimers.

 M. Kimura, Y. Nakano, N. Adachi, Y. Tatewaki, H. Shirai, and N. Kobayashi

 Chem. Eur. J. 15, 2617-2624 (2009). 31) Application of the Perimeter Model to the Assignment of the Electronic Absorption Spectra of Gold(III) Hexaphrins with [4n+2] and [4n] p-Electron Systems.

 A. Muranaka, O. Matsushita, K. Yoshida, S. Mori, M. Suzuki, T. Furuyama, M. Uchiyama, A. Osuka, and N. Kobayashi

 Chem. Eur. J. 15, 3744-3751 (2009).

 32) Synthesis, Spectroscopic and Electrochemical Studies of Pyrazine or Pyridine Ring-Fused Tetraazachlorins, Bacteriochlorins, and Isobacteriochlorins E. A. Makarova, E. V. Dzyuina, T. Fukuda, H. Kaneko, N. Hashimoto, Y. Kikukawa, N. Kobayashi, and E. A. Lukyanets

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 W. S. Durfee

 Inorg. Chem. 48, 164-173 (2009). 33) Electroabsorption Spectra of Directly Linked Tribenzotetraazachlorin-Fullerene Conjugates Having Either

 Electron Donating or Withdrawing Substituents in a Polymer Film

 T. Fukuda, S. Masuda, M. Wahadoszamen, N. Ohta, and N. Kobayashi

 Dalton. 6089-6091 (2009). selected as a cover page. 34) Effect of peripheral fused ring substitution on the optical spectroscopy and electronic structure of metal phthalocyanine complexes

  W. Chidawanyika, J. Mack, S. Shimizu, N. Kobayashi, and T. Nyokong

 J. Porphyrins Phthalocyanines 13, 1053-1062 (2009). 35) Synthesis, Structures, and Optical and Electrochemical Properties of ...

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